Editorial Feature

Caoxite – Occurrence, Properties, and Distribution

The name caoxite is an acronym with two possible meanings. One is for the key chemical components present in the mineral - Calcium and Oxalate. The other is for the Centennial Anniversary Of X-rays, an essential analytical tool in modern mineralogy.

Properties of Caoxite

The following are the key properties of caoxite:

  • Cell Data
    • Space group: P1
    • a = 6.097(1)
    • b = 7.145(1)
    • c = 8.434(1)
    • α = 76.54(1)°
    • β = 70.30(1)°
    • γ = 70.75(1) °
    • Z = 2

  • Crystal Data
    • Triclinic
    • Point group: 1
    • As elongated crystals, tabular on {010}, with polygonal outline, to 0.5mm
    • As crystalline spherulites
    • X-ray powder pattern: 5.52 (vs), 2.834 (s), 7.92 (m), 5.26 (m), 4.99 (m), 3.643 (m), 2.758 (m)

  • Chemical Composition
    Elements Content 1 Content 2
    C2O3 [39.54] 39.54
    CaO 30.03 30.79
    H2O [29.67] 29.67
    Total [99.24] 100.00

  • Optical Properties
    • Optical Class: Biaxial (–)
    • α = 1.483(3) (α’); β = [1.516]; γ = 1.533(3) (γ’)
    • 2V(meas.) = 70(2) °

  • Estimated Properties
    Electron density Bulk density (electron density) = 1.91 g/cm3
    note: Specific gravity of caoxite = 1.85 g/cm3
    Photoelectric PEcaoxite = 2.85 barns/electron
    U=PEcaoxite x ρ electron density = 5.45 barns/cm3
    Fermion index Fermion index = 0.0020479048
    Boson index = 0.9979520952
    Radioactivity
    Caoxite is not radioactive

How to Identify Caoxite

Caoxite can be identified in the field by its colorless structure. Its transparent form has {010} good cleavage. This mineral has a vitreous luster with white streak.

The density of caoxite is 1.85 g/cm3 with a hardness of 2 to 2.5 – between gypsum and finger nail. The fracture on this mineral is brittle – uneven.

Global Distribution

Caoxite is distributed mainly in Italy, from the Cerchiara mine, near Faggiona, Val di Vara, in Liguria.

Occurrence of Caoxite and Useful Mineral Association

Caoxite typically occurs in veinlets cutting metamorphosed Mn–Ba-rich cherts in an obducted ophiolite.

It is often associated with minerals such as quartz, barite and manganese oxides.

References

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