Editorial Feature

Bobierrite - Occurrence, Properties, and Distribution

Bobierrite was named after Pierre Adolphe Bobierre (1823–1881), a French agricultural chemist, who first described the mineral.

Properties of Bobierrite

The following are the key properties of bobierrite:

  • Cell Data
    • Space group: C2/c
    • a = 4.667(1)
    • b = 27.926(8)
    • c = 10.067(3)
    • β = 105.01(2)°
    • Z = 4

  • Crystal Data
    • Monoclinic
    • Point group: 2/m
    • Crystals are usually acicular, fibrous, and lath-shaped, elongated || [001] and flattened on {010} may be diamond-shaped, to 4cm
    • As crystalline aggregates, typically in the form of fans and rosettes, fine-grained, massive
    • X-ray powder pattern: 6.96 (100), 2.94 (27), 8.04 (18), 2.81 (13), 2.41 (12), 3.02 (10), 2.13 (10)

  • Chemical Composition
    Elements Content 1 Content 2 Content 3
    H2O 35.38 34.27 35.41
    P2O5 34.59 34.52 34.88
    MgO 29.97 25.12 29.71
    CaO - 5.71 -
    Total 99.94 99.62 100.00

  • Optical Properties
    • Optical class: Biaxial (+)
    • Orientation: Y = b; Z ^ c = 27°- 29°
    • Dispersion: r < v, weak
    • α = 1.508–1.512; β = 1.514–1.520; γ = 1.541–1.543
    • 2V(meas.) = 71(3)°
    • 2V(calc.) = 73°

  • Estimated Properties
    Electron density Bulk density (electron density) = 2.27 g/cm3
    note: Specific gravity of bobierrite = 2.20 g/cm3
    Photoelectric PEBobierrite = 1.21 barns/electron
    U = PEBobierrite x ρ electron density = 2.75 barns/cm3
    Fermion index Fermion index = 0.01
    Boson index = 0.99
    Radioactivity
    Bobierrite is not radioactive

How to Identify Bobierrite

Bobierrite can be identified in the field by its color variations, such as gray and white. It is sometimes colorless. Its transparent form has {010} perfect cleavage. This mineral has a vitreous luster, with white streak.

The density of bobierrite is 2.195 g/cm3, with a hardness of 2 to 2.5 - between gypsum and finger nail.

Global Distribution

Bobierrite is distributed in the following places:

  • Chile - Found on Mejillones Island
  • Australia - Western Australia in the Pilbara district at Wodgina
  • New Zealand - From Marlborough
  • USA - Found near Edgerton, Pipestone Co. Minnesota
  • Norway - At the Odegarden apatite mines, Bamble
  • Portugal - In the Bendada pegmatite, near Guarda
  • Russia - Fine large crystals found in the Zheleznyi iron mine, Kovdor massif, Kola Peninsula
  • Kenya - Occurs in the Imperial Canyon lava tubes, Northern Chyulu Hills

Occurrence of Bobierrite and Useful Mineral Association

Bobierrite occurs in the chemical alteration of guano deposits; and as a rare alteration product of primary phosphate-bearing minerals.

It is often associated with minerals such as hannayite, schertelite, lithiophilite, sicklerite, purpurite, collinsite, apatite, dolomite, and calcite.

References

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