Editorial Feature

Rittmannite - Occurrence, Properties, and Distribution

Rittmannite is a member of the Whiteite group. It was first discovered in 1989 from Mangualde pegmatite, near Mesquitela, and the Bendada pegmatite, near Guarda, Portugal. It was named after the Swiss volcanologist Alfred Rittmann, who is considered as the founder of European volcanology.

Properties of Rittmannite

The following are the key properties of Rittmannite:

  • Cell Data
    • Space Group: [P2/a] (by analogy to the whiteite group)
    • a = 15.01(4)
    • b = 6.89(3)
    • c = 10.16(3)
    • β = 112.82(25)°
    • Z = 2

  • Crystal Data
    • Monoclinic
    • Point Group: 2/m
    • As crystals, flattened on {001}, pseudohexagonal, to 1mm, in subparallel aggregates
    • X-ray Powder Pattern: 9.38 (s), 2.802 (s), 4.69 (ms), 5.66 (m), 4.93 (m), 4.85 (m), 3.530 (m)

  • Chemical Composition
    Elements Content 1
    P2O5 35.9
    H2O [19.7]
    MnO 18.9
    Al2O3 11.3
    FeO 10.4
    CaO 3.3
    Fe2O3 2.6
    MgO 1.5
    Total [103.6]

  • Optical Properties
    • Optical Class: Biaxial (+)
    • Orientation: X = b; Z ^ c = 7°
    • α = 1.622
    • β = [1.626]
    • γ = [1.654]
    • 2V(meas.) = 43(2)°

  • Estimated Properties
    Electron density Bulk density (electron density) = 2.80 g/cm3
    note: Specific gravity of Rittmannite = 2.81 g/cm3
    Photoelectric PERittmannite = 6.63 barns/electron
    U = PERittmannite x ρElectron density = 18.58 barns/cm3
    Fermion index Fermion index = 0.001
    Boson index = 0.998
    Radioactivity
    Rittmannite is not radioactive

How to Identify Rittmannite

Rittmannite has a light yellow color with white streak. It has indistinct cleavage, vitreous luster, and transparent nature.

The density of rittmannite is 2.81 g/cm3, and its relative hardness is 3.5.

Global Distribution

Rittmannite is distributed in the following places:

  • Mangualde pegmatite, near Mesquitela
  • Bendada pegmatite, near Guarda, Portugal

Occurrence of Rittmannite and Useful Mineral Association

Rittmannite occurs as a very rare mineral in phosphatic nodules in zoned granite pegmatite veins (Mangualde pegmatite, Portugal).

The minerals that are closely related to rittmannite are orthoclase, hureaulite, frondelite, and kryzhanovskite.

References

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