Editorial Feature

Ramsdellite – Occurrence, Properties and Distribution

Ramsdellite is named after the American mineralogist Lewis S Ramsdell of the University of Michigan. He was the first person to describe the mineral. It is formed by pyrolusite inversion or conducting oxidative dehydrogenation of groutite.

Chemical Formula – Mn4+O2

Properties of Ramsdellite

The following are the key properties of Ramsdellite

  • Cell Data
    • Space Group: Pbnm
    • a = 4.533
    • b = 9.27
    • c = 2.866
    • Z = 4
  • Crystal Data
    • Orthorhombic
    • Point Group: 2/m 2/m 2/m
    • Crystals upto 1 cm are normally as pseudomorphs similar to groutite crystals; fibrous, platy and massive
    • X-ray powder pattern: 4.08 (10), 2.53 (8), 1.60 (7), 1.64 (6), 2.13 (5), 1.88 (5), 1.46 (5)
  • Chemical Composition
    Elements Content 1 Content 2
    SiO2 0.36 0.42
    MnO2 95.02 97.14
    Al2O3 0.72 0.48
    Fe2O3 0.22 0.34
    MnO 0.00 0.00
    ZnO 0.25 n.d
    MgO 0.00 0.12
    Cao 1.12 0.00
    BaO 0.00 0.00
    Na2O n.d 0.31
    K2O n.d 0.41
    H2O+ 1.39
    H2O- 0.05
    H2O 1.24
  • Optical Properties
    • Class – Biaxial
    • R1-R2 : n.d
  • Estimated Properties
    Electron density Bulk density (electron density) = 4.52 g/cm3
    note: Specific gravity of ramsdellite = 4.79 g/cm3
    Photoelectric PERamsdellite = 16.61 barns/electron
    U=PERamsdellite x ρElectron Density= 75.02 barns/cc
    Fermion index Fermion Index = 0.0001766733
    Boson Index = 0.9998233267
    Radioactivity Ramsdellite is not radioactive

How to Identify Ramsdellite

Ramsdellite is opaque, steel gray to iron black and yellowish white in reflected light. It has a brilliant metallic luster.

Global Distribution

Ramsdellite is distributed in the following places:

  • in the USA, from Lake Valley, Sierra Co New Mexico
  • in the Artillery Mountains, Mohave Co., and at the Mistake mine, Yavapai Co., Arizona
  • from the Idarado mine, near Telluride, San Miguel Co., Colorado
  • in the Monroe-Tener mine, near Chisholm, St. Louis Co., Minnesota.
  • Along the East River, Pictou Co., Nova Scotia, Canada.
  • In Mexico, at Los Gavilanes, Baja California.
  • In India, from Dongari Buzurg, Bhandara, Madhya Pradesh.
  • At the Iron Monarch quarry, Iron Knob, South Australia.
  • From the Otoshibetsu and Tanno mines, Hokkaido, and elsewhere in Japan.
  • At Horni Blatna (Platten), Czech Republic
  • From B¨utten-Adenstadt, Lower Saxony, and the Clara Mine, near Oberwolfach, Black Forest, Germany
  • At Gebel To Yu, Yoider, and Um Bogna, Egypt
  • From Hotazel, near Kuruman, Cape Province, South Africa

Occurrence of Ramsdellite and Useful Mineral Association

Ramsdellite is a secondary mineral in manganese deposits, formed by inversion of pyrolusite or oxidative dehydrogenation of groutite. It is associated with minerals such as Pyrolusite, hollandite, cryptomelane and coronadite.

References

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