Afghanite – Occurrence, Properties, and Distribution

Topics Covered

Introduction to Afghanite
Properties of Afghanite
How to Identify Afghanite
Global Distribution
Occurrence of Afghanite and Useful Mineral Association
References

Introduction to Afghanite

Chemical Formula - (Na,Ca,K)8(Si,Al)12O24(SO4,Cl,CO3)3• H2O

Afghanite was named after Afghanistan, the country where it was first discovered. It belongs to the cancrinite group.

Properties of Afghanite

The following are the key properties of afghanite:

  • Cell Data
    • Space group: P63/mmc, P63/mc, or P62c
    • a = 12.77(3)
    • c = 21.35(4)
    • Z = 3

 

  • Crystal Data
    • Hexagonal
    • Point group: 6/m 2/m 2/m, 6mm, 6 m2
    • Stout to slender
    • Thin tabular laths
    • Rounded grains
    • X-ray powder pattern: 3.688 (100), 3.298 (100), 4.82 (80), 3.997 (60), 2.865 (60), 2.130 (60), 1.792 (60)

 

  • Chemical Composition
    Elements Content 1 Content 2
    SiO2 30.8 32.96
    Al2O3 25 25.45
    CaO 16.5 11.98
    Na2O 12.6 12.52
    SO3 8.5 10.82
    Cl 4.6 3.98
    K2O 2.7 3.07
    - O=Cl2 1.0 0.9
    H2O 0.7 -
    CO2 0.4 -
    Total 100.8 99.88

 

  • Optical Properties
    • Transparent
    • Optical class: Uniaxial (+)
    • ω = 1.523(2)
    • ε = 1.529(2)

 

  • Estimated Properties
    Electron density Bulk density (electron density) = 2.57 g/cm3
    note: Specific gravity of afghanite = 2.60 g/cm3
    Photoelectric PEAfghanite = 3.25 barns/electron
    U = PEAfghanite x ρ electron density = 8.37 barns/cm3
    Fermion index Fermion index = 0.0072
    Boson index = 0.9927
    Radioactivity
    Afghanite is not radioactive

How to Identify Afghanite

Afghanite can be identified in the field by its blue color. It can also be colorless. Its transparent form has {1010} perfect cleavage. This mineral has a vitreous luster, with a white streak. The fracture on this mineral is conchoidal.

The density of Afghanite is 2.55 to 2.65 g/cm3, with a hardness of 5.5 to 6 - between a knife blade and orthoclase.

Global Distribution

Afghanite is distributed in the following places:

  • Afghanistan - At Sar-e-Sang, Badakhshan Province
  • Italy - At the Pitigliano quarry, near Grosseto, Tuscany; on Monte Somma, Campania; from Vetralla and Bassano, Latium
  • Russia - In the Malaya Bystraya and Tultuy lazurite deposits, near Lake Baikal, and in other unspecified deposits in eastern Siberia
  • Tajikistan - From Lyadzhuar-Darinsk, Pamir Mountains
  • USA - In the Edwards mine, Edwards, St. Lawrence Co. New York
  • Canada - At Lake Harbour, Baffn Island, Newfoundland
  • Germany - Rhineland-Palatinate, Ettringen, Bellerberg volcano, Caspar quarry

Occurrence of Afghanite and Useful Mineral Association

Afghanite occurs in thin veinlets cutting lazurite crystals; in silicfied limestone xenoliths in pumice.

It is often associated with minerals such as sodalite, nepheline, lazurite, olivine, vesuvianite, calcite, diopside, pyrite, and phlogopite.

References

 

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