Editorial Feature

Bieberite – Occurrence, Properties, and Distribution

Bieberite was named after the place of first-noted occurrence - Bieber, Germany. It belongs to the melanterite group.

Properties of Bieberite

The following are the key properties of bieberite:

  • Cell Data
    • Space group: P21/c (synthetic)
    • a = 14.040
    • b = 6.495
    • c = 10.923
    • β = 105.27°
    • Z = 4

  • Crystal Data
    • Monoclinic
    • Point group: 2/m
    • As stalactites, and crusts of minute crystals
    • X-ray powder pattern: 4.87 (100), 3.76 (75), 4.82 (55), 2.725 (25), 3.71 (20), 4.02 (14), 3.25 (14)

  • Chemical Composition
Elements Content 1 Content 2
H2O 46.83 44.86
P2O5 29.05 28.48
CoO 19.91 26.66
MgO 3.86 -
Total 99.65 100.00

  • Optical Properties
    • Optical class: Biaxial (-)
    • Orientation: Y = b; Z ∧ c = 29°18’
    • α = 1.475–1.477; β = 1.482–1.483; γ = 1.488–1.489
    • 2V(meas.) = 88°01’

  • Estimated Properties
Electron density Bulk density (electron density) = 1.96 g/cm3
note: Specific gravity of Bieberite = 1.90 g/cm3
Photoelectric PE Bieberite = 7.49 barns/electron
U = PE Bieberite x ρ electron density = 14.67 barns/cm3
Fermion index Fermion index = 0.0011635864
Boson index = 0.9988364136
Radioactivity Bieberite is not radioactive

How to Identify Bieberite

Bieberite can be identified in the field by its color variations, such as pinkish-red and flesh pink. Its translucent form has {001} perfect cleavage. This mineral has a vitreous–dull luster, with white streak. The fracture on this mineral is uneven and flat.

The density of bieberite is 1.9 g/cm3, with a hardness of 2 - approximate to gypsum.

Global Distribution

Bieberite is distributed in the following places:

  • Germany - From Bieber, near Hanau, Hesse; at Siegen, Westphalia; from Wittichen, Black Forest
  • England - In the Penberthy Croft mine, St. Hilary, and at Wheal Alfred, Phillack, Cornwall
  • Spain - From Minas de Riotinto, Huelva Province
  • Austria - At Leogang, and in the Rauris Valley, Salzburg
  • Australia - In the Dome Rock copper mine, South Australia
  • Zimbabwe - From the Copper King mine, Lomagundi district
  • France - At Chalanches, Isere
  • USA - At Island Mountain, Trinity Co. California; from Ajo, Pima Co. Arizona; and in the Dolly prospect, Emery Co. Utah
  • Chile - From Tres Puntos, near Copiapo, Atacama

Occurrence of Bieberite and Useful Mineral Association

Bieberite occurs in an uncommon oxidation product of cobalt-bearing sulfide–arsenides.

It is often associated with minerals such as erythrite, annabergite, pharmacolite, linnaeite, and cobaltite.

References

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