Editorial Feature

Ilesite – Occurrence, Properties, and Distribution

Ilesite is named after the American metallurgist Malvern Wells Iles of Denver, Colorado, USA. He performed the first chemical analysis of this mineral.

Ilesite belongs to the Rozenite group, and was discovered in 1881.

Properties of Ilesite

The following are the key properties of ilesite:

  • Cell Data
    • Space group: P21/n (synthetic MnSO4 •4H2O)
    • a = 5.94(1)
    • b = 13.76(2)
    • c = 8.01(1)
    • β = 90°48(10)'
    • Z = 4

  • Crystal Data
    • Monoclinic
    • Point group: 2/m
    • As prismatic crystals, to 1mm
    • Commonly aggregated as vein fillings and incrustations
    • X-ray powder pattern: (ICDD 32-651)
    • 4.55 (100), 5.5 (90), 4.01 (90), 2.99 (90), 3.46 (80), 3.28 (80), 3.01 (70)

  • Chemical Composition
    Elements Content
    SO3 36.07
    H2O 31.60
    MnO 22.31
    ZnO 5.97
    FeO 4.18
    Total 100.13

  • Optical Properties
    • Optical class: Biaxial (–)
    • Orientation: Y = b; Z ^ c = 5°; α = 1.508; β= 1.518; γ = 1.522
    • 2V (meas.) = Moderate

  • Estimated Properties
    Electron density Bulk density (electron density) = 2.29 gm/cm3
    note: Specific gravity of ilesite = 2.26 gm/cm3
    Photoelectric PEIlesite = 9.31 barns/electron
    U = PEIlesite x ρElectron density = 21.33 barns/cm3
    Fermion index Fermion index = 0.0054171149
    Boson index = 0.9945828851
    Radioactivity
    Ilesite is not radioactive

How to Identify Ilesite

Ilesite can be identified in the field by its green, greenish-white, and white variations. It is transparent, and is made of a number of single crystals that are non-fluorescent. It has crust-like aggregates on matrix, and is non-magnetic with a glassy lustre and white streak.

The density of ilesite is 2.261 g/cm3, with a hardness of 2 to 3 – between gypsum and calcite.

Global Distribution

Globally, ilesite can be found in the following locations:

  • USA - from the McDonnell claim, Montezuma district, Hall Valley, Park Co. and at the Penn mine, Summit Co. Colorado
  • Czech Republic - Chvaletice
  • Japan - Jokoku mine, southwest Hokkaido
  • Canada - Silver King mine, Galena Hill, Yukon Territory

Occurrence of Ilesite and Useful Mineral Association

Ilesite occurs as a rare secondary mineral in the oxidized zones of sulfide deposits.

It is often associated with minerals such as pyrite, rozenite, epsomite, sphalerite, galena, copiapite, chvaleticeite, gypsum, and melanterite.

References

http://www.mindat.org/min-2009.html

http://webmineral.com/data/Ilesite.shtml

http://rruff.geo.arizona.edu/doclib/hom/ilesite.pdf

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