Editorial Feature

Chloritoid - Occurrence, Properties, and Distribution

Chlorotoid is a silicate mineral that was first described in 1837, from the Ural Mountains region of Russia. It was named for its similarities of the chlorite-group minerals.

Properties of Chloritoid

The following are the key properties of Chloritoid:

  • Cell Data
    • Space Group: C2/c
    • a = 9.50(3)
    • b = 5.50(2)
    • c = 18.22(5)
    • β = 101°57(5)'
    • Z = 4
      Or
    • Space Group: C1
    • a = 9.46(1)
    • b = 5.50(1)
    • c = 9.15(1)
    • α = 97:05(2)°
    • β = 101:56(2)°
    • γ = 90:10(2)°
    • Z = 4

  • Crystal Data
    • Monoclinic or triclinic, both pseudohexagonal
    • Point Group: 2/m or 1
    • Rarely as rosettes of pseudohexagonal tabular crystals; commonly coarsely foliated with foliae
    • typically curved or bent; massive
    • Twinning: Common on {001}, may be lamellar; twin axes [100], [110], and [130] observed
    • X-ray Powder Pattern: 4.498 (100), 4.449 (100), 2.963 (90), 1.5813 (80), 2.367 (70), 2.306 (70), 2.639 (50)

  • Chemical Composition
    Elements Content
    Al2O3 40.12
    FeO 27.06
    SiO2 23.91
    H2O+ 7.03
    Fe2O3 1.23
    MgO 0.51
    TiO2 0.20
    MnO 0.16
    CaO 0.04
    F 0.01
    H2O- 0.01
    K2O trace
    Total 100.28

  • Optical Properties
    • Optical Class: Biaxial (+) or (-)
    • Pleochroism: X = olive-green to yellow; Y = grayish blue to blue; Z = colorless to pale greenish-yellow
    • Orientation: X or Y = b (monoclinic)
    • Z ^ c = 2°-30°
    • Y ˜ b (triclinic)
    • Dispersion: r > v; strong
    • α = 1.705-1.730
    • β = 1.708-1.734
    • γ = 1.712-1.740
    • 2V(meas.) = ∼45°-70°

  • Estimated Properties
    Electron density Bulk density (electron density) = 3.43 g/cm3
    note: Specific gravity of Chloritoid = 3.47 g/cm3
    Photoelectric PEChloritoid = 5.82 barns/electron
    U = PEChloritoid x ρElectron density = 19.95 barns/cm3
    Fermion index Fermion index = 0.01
    Boson index = 0.99
    Radioactivity
    Chloritoid is not radioactive

How to Identify Chloritoid

Chloritoid is non-fluorescent and occurs in a range of colors, from dark gray to dark green, grayish-black, green-black, and green-gray. It has a transparent to translucent appearance, with pearly luster and green-gray streak. Its fractures are brittle, like that of non-metallic minerals and glasses. It exhibits two-dimensional platy forms, or massive crystal forms.

The hardness of the mineral is 6.5, and its average density is 3.54 g/cm3.

Global Distribution

Chloritoid is distributed in the following places:

  • Kosoi Brod, Mramorskii Zavod, south of Yekaterinburg, Russia
  • Salmchateau, near Ottre, Ardennes Mountains, Belgium
  • Nadels and Zermatt, Valais, Switzerland
  • PrÄagraten, Tirol, Austria
  • Along the coast between Stonehaven and Aberdeen, Scotland
  • Tintagel, Cornwall, England
  • Natick, Kent Co. Rhode Island, USA
  • Chester, Hampden Co. Massachusetts
  • Clove Valley, Duchess Co. New York
  • Bull Mountain, Patrick Co. Virginia
  • Chibougamau and St. Giles, Quebec, Canada
  • Kalgoorlie, Western Australia.

Occurrence of Chloritoid and Useful Mineral Association

Chloritoid occurs in regionally metamorphosed pelitic sediments, lower grade staurolite zones, garnet, schists in the biotite, quartz-carbonate veins, and other hydrothermal environments.

References

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