Editorial Feature

Bariopyrochlore – Occurrence, Properties, and Distribution

Bariopyrochlore was named by the IMA committee on pyrochlore nomenclature, based on the major content, barium, in the composition, and its membership of the pyrochlore group.

Properties of Bariopyrochlore

The following are the key properties of bariopyrochlore:

  • Cell Data
    • Space group: Fd3m
    • a = 10.562(6)
    • Z = 8

  • Crystal Data
    • Cubic
    • Point group: 4/m 3 2/m
    • As crude to anhedral crystals, to 1mm, showing cube and octahedron faces; granular, porous due to alteration or recrystallization
    • X-ray powder pattern: 3.044 (100), 6.09 (80), 1.864 (70), 1.590 (70), 1.0164 (60), 3.18 (50), 1.210 (50)

  • Chemical Composition
    Elements Content 1 Content 2
    Nb2O3 69.06 65.60
    BaO 12.88 15.31
    H2O+ 4.11 8.17
    SrO 6.60 trace
    TiO2 3.87 4.63
    S Ce2O3 2.06 2.17
    CaO 0.86 1.37
    ThO2 0.62 0.92
    Ta2O5 0.23 0.57
    MgO - 0.57
    FeO 0.44 -
    Na2O 0.28 0.23
    K2O 0.15 0.23
    PbO - 0.23
    F trace -
    Total [101.16] [100.00]

  • Optical Properties
    • Optical class: Isotropic
    • n = 2.07–2.11

  • Estimated Properties
    Electron density Bulk density (electron density) = 3.67 g/cm3
    note: Specific gravity of bariopyrochlore = 4.00 g/cm3
    Photoelectric PEbariopyrochlore = 134.09 barns/electron
    U = PEbariopyrochlore x ρ electron density = 491.47 barns/cm3
    Fermion index Fermion index = 0.02
    Boson index = 0.98
    Radioactivity
    Bariopyrochlore is not radioactive

How to Identify Bariopyrochlore

Bariopyrochlore can be identified in the field by its color variations, such as green-gray, and yellow-gray. Its transparent to translucent form has {111} indistinct, {111} indistinct, {111} indistinct cleavage. This mineral has a resinous luster, with white streak. The fracture on this mineral is brittle-conchoidal.

The density of bariopyrochlore is 4 g/cm3, with a hardness of 4.5 to 5 – approximate to near apatite.

Global Distribution

Bariopyrochlore is distributed in the following places:

  • Tanzania - From the Mbeya carbonatite, Panda Hill, near Mbeya
  • Congo (Zaire) - From the Bingo deposit, Kivu Province
  • Kenya - In the Mrima Hill carbonatite
  • Brazil - In a deposit of several hundred million tons at Arax´a, Minas Gerais, and in the Catalao II carbonatite, Goias
  • Russia - At an undefined locality in Primorskiy Kray
  • USA - From Dehnel’s pit, Stettin, Marathon Co. Wisconsin

Occurrence of Bariopyrochlore and Useful Mineral Association

Bariopyrochlore occurs at the contact zone of a highly weathered, biotite-rich rock, in a roof pendant in a carbonatite, in weathered carbonatite, and in an alkalic aegerine-albite-microcline metasomatite in nepheline syenite.

It is often associated with minerals such as biotite, fluorite, quartz, kaolinized feldspar, zircon, chlorite, plagioclase, apatite, rutile, zircon, hematite, limonite, and aegirine.

References

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