Editorial Feature

Brookite – Occurrence, Properties, and Distribution

Brookite was named after Henry James Brooke (1771–1857), an English crystallographer and mineralogist.

Properties of Brookite

The following are the key properties of brookite:

  • Cell Data
    • Space group: Pcab
    • a = 5.4558
    • b = 9.1819
    • c = 5.1429
    • Z = 8

  • Crystal Data
    • Orthorhombic
    • Point group: 2/m2/m2/m
    • As crystals, to 12cm, typically tabular on {010} and elongated and striated || [001] rarely tabular on {001}
    • Commonly pyramidal {111} or pseudohexagonal with {120} and {111}
    • Twinning: On {120}, uncertain
    • X-ray powder pattern: 3.51 (100), 2.900 (90), 3.47 (80), 1.893 (30), 1.662 (30), 2.476 (25), 1.691 (20)

  • Chemical Composition
    Elements Content 1 Content 2
    TiO2 98.59 98.77
    Fe2O3 1.41 1.48
    Total 100.00 100.25

  • Optical Properties
    • Optical Class: Biaxial (+)
    • Pleochroism: very weak; yellowish, reddish, orange to brown
    • Orientation: Z = b
    • Dispersion: r > v, very strong, with crossed axial dispersion
    • Absorption: Z >Y >X
    • α = 2.5831 β = 2.5843 γ = 2.7004 2V(meas.) = 0° – 28°, variable with wavelength
  • Estimated Properties
    Electron density Bulk density (electron density) = 3.92 g/cm3
    note: Specific gravity of brookite = 4.12 g/cm3
    Photoelectric PEBrookite = 10.03 barns/electron
    U=PEBrookite x ρ electron density = 39.34 barns/cm3
    Fermion index Fermion index = 0.07
    Boson index = 0.93
    Radioactivity
    Brookite is not radioactive

How to Identify Brookite

Brookite can be identified in the field by its color variations, such as brown, light brown, dark brown, dark reddish-brown, and orange. Its transparent to translucent to opaque form has {120} an indistinct cleavage. This mineral has a sub-metallic luster with yellowish-white streak. The fracture on this mineral is sub-conchoidal.

The density of brookite is 4.1 to 4.14 g/cm3 with a hardness of 5.5 to 6 - between a knife blade and orthoclase.

Global Distribution

Brookite is distributed in the following places:

  • Wales - At Fron Oleu, near Tremadog, Gwynned
  • Switzerland - In the Maderanthal and Griessertal, Uri, at Salvan, Valais
  • Austria - Found near Pragraten and Virgen, Tirol
  • France - From Bourg d’Oisans, Isere
  • Norway - From Hardangervidda
  • Russia - At Atliansk, near Miass, Ilmen Mountains, Southern Ural Mountains, and large crystals in the Dodo mine, about 100km west-north-west of Saranpaul, Subpolar Ural Mountains.
  • Italy - at Monte Bregaceto, near Genoa, Liguria
  • Brazil - In the diamond placers of Bahia and Diamantina, Minas Gerais
  • USA - At Magnet Cove, Hot Spring Co. Arkansas; Ellensville, Ulster Co. New York; and near Powderhorn, Gunnison Co. Colorado

Occurrence of Brookite and Useful Mineral Association

Brookite occurs in an accessory mineral in alpine veins in gneiss and schist; in contact metamorphic zones and hydrothermal veinlets; and in a common detrital mineral.

It is often associated with minerals such as anatase, rutile, titanite, chlorite, orthoclase, hematite, calcite, quartz, and muscovite.

References

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